Superparamagnetism of Artificial Glasses Based on Rocks: Experimental Data and Theoretical Modeling

Author:

Kharitonskii Petr1,Sergienko Elena2ORCID,Ralin Andrey3,Setrov Evgenii4,Sheidaev Timur4ORCID,Gareev Kamil4ORCID,Ustinov Alexander5,Zolotov Nikita6,Yanson Svetlana2,Dubeshko Danil2

Affiliation:

1. Ioffe Physical Technical Institute, Russian Academy of Sciences, 194021 Saint Petersburg, Russia

2. Department of Earth Physics, Saint Petersburg University, 199034 Saint Petersburg, Russia

3. Institute of Mathematics and Computer Technologies, Far Eastern Federal University, 690922 Vladivostok, Russia

4. Department of Micro and Nanoelectronics, Saint Petersburg Electrotechnical University “LETI”, 197022 Saint Petersburg, Russia

5. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022 Vladivostok, Russia

6. Institute of Precambrian Geology and Geochronology, Russian Academy of Sciences, 199034 Saint Petersburg, Russia

Abstract

Artificial glasses containing nanoscale inclusions of iron oxides, including magnetite and hematite, were obtained via the method of the high-temperature melting of rocks. The main factors influencing the magnetic properties of glasses are the composition of the initial charge and the conditions of cooling of the melt. The data of magnetic granulometry and frequency-field dependencies of magnetic susceptibility showed the presence of a sufficiently large superparamagnetic fraction in the samples. Coordinated theoretical modeling using two independent models that take into consideration possible the chemical inhomogeneity of particles and magnetostatic interaction between them made it possible to calculate hysteresis characteristics corresponding to the experiment and to estimate ferrimagnetic concentrations in the samples, including the superparamagnetic fraction.

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

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