Synthesis and Characterization of the Amidomanganates Rb2[Mn(NH2)4] and Cs2[Mn(NH2)4]

Abstract

We report the successful synthesis of Rb2[Mn(NH2)4] and Cs2[Mn(NH2)4] from ammonothermal conditions at 723 K and pressures above 850 bar. Both compounds were obtained single phase according to powder X-ray diffraction. The crystal structures were determined by single crystal X-ray diffraction. For Rb2[Mn(NH2)4] we have obtained the high-temperature phase. The structures are analyzed with respect to the earlier reported alkali metal amidomanganates. Upon heating in inert atmosphere Cs2[Mn(NH2)4] decomposes to manganese nitrides. IR spectroscopic results are reported.