Effect of the Solvent on the Basic Properties of Mg–Al Hydrotalcite Catalysts for Glucose Isomerization

Abstract

We suggested the existence of a relationship between the base properties of Mg–Al hydrotalcite catalysts and the solvents employed in the industrially important isomerization of glucose produce fructose. We prepared Mg–Al hydrotalcite catalysts with different Mg/Al atomic ratios to tune the basic properties of the catalyst. The prepared catalysts were used in the glucose isomerization conducted in various solvents. Experimental results confirmed that the catalysts exhibited different activities in the different solvents. We also implemented the Hammett indicator method, which allows to analyze the basic properties of the catalysts in various solvents. According to evidence, the basic properties of the catalysts varied substantially in different solvents. Notably, increases in the catalysts’ base properties matched the observed increases in fructose yield of the glucose isomerization. Consequently, we suggested that, in order to prepare efficient Mg–Al hydrotalcite catalysts for glucose isomerization, the interaction between the solvent used to conduct the reaction and the basic properties of the catalyst, which are in turn influenced by the solvent, should be considered.