Selective Leaching of Rare Earth Elements (REEs) from Eudialyte Concentrate after Sulfation and Thermal Decomposition of Non-REE Sulfates

Abstract

Eudialyte, a sodium rich zirconosilicate, is one of the promising sources for REEs (rare earth elements), particularly for HREEs + Y (heavy rare earth elements and yttrium). The key challenge in hydrometallurgical processing is the prevention of silica gel formation and REE separation from resulting multi-element leach solutions. This study deals with the selective extraction of REE from eudialyte concentrate by selective roasting. In this method, metal ions are converted into sulfates, followed by the decomposition of non-REE sulfates in a roasting step and the water leaching of the calcine. The effect of acid addition, roasting temperature, roasting time, pulp density and leaching time is studied. For sufficient conversion of REEs into sulfates, sulfuric acid is added in excess. At a roasting temperature of ≥750 °C sulfates of zirconium, hafnium, niobium, aluminum and iron decompose into sparingly soluble compounds, while REE and manganese sulfates remain stable up to a roasting time of 120 min. The silica present in the calcine is found to be metastable even after roasting. The amount of leached Si4+ is dependent predominantly on the pH value of the leaching medium. Applying the method, REEs can be efficiently separated from zirconium, hafnium, niobium, aluminum and iron. However, only diluted solutions can be produced. Water leaching of calcine at high solid/liquid ratios causes REE losses resulting from formation of double sulfates and gypsum. The acid excess removed from the reaction mixture in the roasting stage can be simply recovered by treatment of the gas phase.