Assessment of CH4 and CO2 Emissions from a Gas Collection System of a Regional Non-Hazardous Waste Landfill, Harmanli, Bulgaria, Using the Interrupted Time Series ARMA Model

Author:

Borisova Daniela1,Kostadinova Gergana2,Petkov Georgi2,Dospatliev Lilko3,Ivanova Miroslava4ORCID,Dermendzhieva Diyana2,Beev Georgi5ORCID

Affiliation:

1. Ekoresurs Harmanli Ltd., 6450 Harmanli, Bulgaria

2. Department of Applied Ecology and Animal Hygiene, Faculty of Agriculture, Trakia University, 6000 Stara Zagora, Bulgaria

3. Department of Pharmacology, Animal Physiology and Physiological Chemistry, Faculty of Veterinary Medicine, Trakia University, 6000 Stara Zagora, Bulgaria

4. Department of Informatics and Mathematics, Faculty of Economics, Trakia University, 6000 Stara Zagora, Bulgaria

5. Department of Biochemistry, Microbiology and Physics, Faculty of Agriculture, Trakia University, 6000 Stara Zagora, Bulgaria

Abstract

Municipal solid waste (MSW) landfills are among the major sources of greenhouse gas (GHG) emissions affecting global warming and the Earth’s climate. In Bulgaria, 53 regional non-hazardous waste landfills (RNHWL) are in operation, which necessitates conducting studies to determine the environmental risk from the emitted GHGs. This study attempted to assess the CH4 and CO2 emissions from three gas wells of a cell (in active and closed phases, each of 2.5 years duration) in an RNHWL, Harmanli (41°54′24.29″ N; 25°53′45.17″ E), based on monthly in situ measurements by portable equipment, using the Interrupted Time Series (ITS) ARMA model. The obtained results showed a significant variation of the CH4 and CO2 concentrations (2.06–15.1% v/v) and of the CH4 and CO2 emission rates (172.81–1762.76 kg/y) by gas wells (GWs), months and years, indicating the dynamics of the biodegradation of the deposited waste in the areas of the three GWs. Throughout most of the monitoring period (2018–2022), the CH4 concentrations were higher than the CO2 concentrations (% v/v), while CO2 emissions were lower than CH4 emissions (kg/y), a fact that could be explained by the differences in the mass of the two gases. The emissions rates of both gases from GW2 dominated over those from GW1 and GW3, giving a reason to determine the zone of GW2 as a hotspot of Cell-1. On the whole, CH4 and CO2 emission rates were higher in the winter (December–February) and partly in the spring (March–May) compared to summer–autumn (June–November). However, the CH4 and CO2 concentrations and emissions decreased drastically after the Cell-1 closure. The CH4/CO2 ratio (0.68–2.01) by months and gas wells demonstrated a great sensitivity, making it a suitable indicator for the assessment of organic waste biodegradation level in the landfills. The ITS ARMA model confirmed the negative and significant effect of the cell closure on CH4 and CO2 emissions; the correlations found between predicted and observed values were strong and positive (0.739–0.896).

Funder

Bulgarian Ministry of Education and Science

Publisher

MDPI AG

Subject

Atmospheric Science,Environmental Science (miscellaneous)

Reference105 articles.

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3