[6-(Thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate-Reference-Cited by-同舟云学术

[6-(Thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate

Published:2023-03-16 Issue:1 Volume:2023 Page:M1605
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Kouvatsis Panagiotis¹^ORCID,Glykos Dimitrios¹,Plakatouras John C.¹²,Malandrinos Gerasimos¹^ORCID

Affiliation:

1. Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

2. Institute of Materials Science and Computing, University Research Center of Ioannina, 451 10 Ioannina, Greece

Abstract

The novel heteroleptic copper (I) complex [6-(thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) copper(I) tetrafluoroborate (1), formulated as [CuL(PPh3)2]BF4, was synthesized in two steps, utilizing the diimine type ligand L = 6-(thiophen-2-yl)-2,2′-bipyridine and triphenylphosphine (PPh3). The compound was characterized both in the solid state and in solution by employing single crystal X-ray diffraction, IR, UV, and NMR spectroscopies. The complex is an orange emitter that demonstrates a photoluminescence quantum yield of 2.6% in the solid state.

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2023/1/M1605/pdf

Reference27 articles.

1. Neutral copper(i) phosphorescent complexes from their ionic counterparts with 2-(2′-quinolyl)benzimidazole and phosphine mixed ligands;Min;Dalton Trans.,2010

2. Novel Heteroleptic CuI Complexes with Tunable Emission Color for Efficient Phosphorescent Light-Emitting Diodes;Zhang;Adv. Funct. Mater.,2007

3. Highly Efficient Electroluminescence from Green-Light-Emitting Electrochemical Cells Based on CuI Complexes;Zhang;Adv. Funct. Mater.,2006

4. Highly Luminescent CuI Complexes for Light-Emitting Electrochemical Cells;Armaroli;Adv. Mater.,2006

5. Luminescent mononuclear mixed ligand complexes of copper(i) with 5-phenyl-2,2′-bipyridine and triphenylphosphine;Safin;Dalton Trans.,2015

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, Spectroscopic Characterization, and Photophysical Studies of Heteroleptic Silver Complexes Bearing 2,9-Bis(styryl)-1,10-phenanthroline Ligands and Bis[(2-diphenylphosphino)phenyl] Ether;Inorganics;2024-05-02

2. Diiodido-bis{N-[2-(diphenylphosphino)benzylidene]benzylamine-κ2N,P}dicopper(I);Molbank;2024-04-18

3. [6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate;Molbank;2023-09-13