Effect of Cerium (IV) Oxide Particle Size on Polydimethylsiloxane Polymer to Form Flexible Materials against Ionizing Radiation

Abstract

This study aims to investigate the impact of CeO2 content and particle size on the radiation shielding abilities of polydimethylsiloxane, also known as silicon rubber (SR). We prepared different SR samples with 10, 30, and 50% of micro and nano CeO2 and we measured the linear attenuation coefficient (LAC) for these samples. We found that the LAC of the SR increases by increasing the CeO2 and all prepared SR samples had higher LACs than the pure SR. We examined the effect of the size of the particles on the LAC and the results demonstrated that the LAC for nano CeO2 is higher than that of micro CeO2. We investigated the half value layer (HVL) for the prepared SR samples and the results revealed that the SR with 10% micro CeO2 had a greater HVL than the SR with 10% nano CeO2. The HVL results demonstrated that the SR containing nanoparticles had higher attenuation effectiveness than the SR with micro CeO2. We also prepared SR samples containing CeO2 in both sizes (i.e., micro and nano) and we found that the HVL of the SR containing both sizes was lower than the HVL of the SR with nano CeO2. The radiation protection efficiency (RPE) at 0.059 MeV for the SR with 10% micro and nano CeO2 was 94.2 and 95.6%, respectively, while the RPE of SR containing both sizes (5% micro CeO2 + 5% micro CeO2) was 96.1% at the same energy. The RPE results also indicated that the attenuation ability was improved when utilizing the micro and nano CeO2 as opposed to the micro CeO2 or nano CeO2 at 0.662, 1.173, and 1.333 MeV.