Affiliation:
1. Department of Mechanical Engineering, Lassonde School of Engineering York University Toronto Ontario M3J 1P3 Canada
Abstract
AbstractPoly(vinylidenefluoride) with enhanced electroactive properties is of great interest in energy harvesting and sensing applications. This study aims to elucidate the effects of processing parameters in extrusion, using a desktop extruder or a microcompounder, on the polymorphism of the fabricated poly(vinylidenefluoride) filaments. All samples were characterized by differential scanning calorimetry, Fourier‐transform infrared spectroscopy, and electromechanical testing. Statistical analyses were conducted to correlate the processing parameters with the poly(vinylidenefluoride) filaments' crystal structures. Experimental results revealed that the optimal extrusion temperature at 220°C and stretching ratio of 4.5 to 6.5 would yield poly(vinylidenefluoride) filaments with a degree of crystallinity of up to 58% of which 80% is β‐phase crystals. The finding of this manuscript has the potential to promote the use of poly(vinylidenefluoride) filaments in the fused filament fabrication.
Funder
Natural Sciences and Engineering Research Council of Canada
Subject
Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry