Affiliation:
1. College of Engineering and Applied Sciences State Key Laboratory of Analytical Chemistry for Life Science Nanjing National Laboratory of Microstructures Nanjing University Nanjing Jiangsu 210023 P. R. China
Abstract
AbstractIn order to achieve a high color‐rendering index (CRI) and low correlated color temperature (CCT) indoor lighting, single‐component phosphors with broad‐band dual emission are in high demand for white‐light‐emitting diodes (WLEDs). However, phosphors with such fluorescent properties are rare at present. Herein, we report a facile solid‐state chemical method for the synthesis of single‐component phosphor with broad‐band emission and a large Stokes shift that can meet the requirements of future white‐light sources. These new tetrabutylammonium copper halides phosphors have excellent warm white emission characteristics, and their luminescence peaks are located at 494 and 654 nm. The optimized photoluminescence (PL) quantum yield can reach 93.7 %. The typical CIE coordinate of the as‐fabricated WLED is at (0.3620, 0.3731) with a CRI of 89 and low CCT of 4516 K.
Funder
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
4 articles.
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