Affiliation:
1. Dipartimento di Chimica Materiali e Ingegneria Chimica “Giulio Natta” Politecnico di Milano Via Luigi Mancinelli 7 20131 Milan Italy
2. INSTM Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali Florence 50121 Italy
Abstract
AbstractIn general, due to the lack of efficient specific molecular interactions, achieving host–guest molecular recognition inside large and neutral metal–organic cages (MOCs) is challenging. Preferential molecular recognition of aromatics using the internal binding sites of interlocked icosahedral (i. e., spherical) M12L8 MOCs within poly‐[n]‐catenane (1) is reported. The guest absorption was monitored directly in the solid‐state by consecutive single‐crystal‐to‐single‐crystal (SCSC) reactions in a gas‐solid environment, in single‐crystal X‐ray diffraction (SC‐XRD) experiments. The preferential guest uptake was corroborated by density functional theory (DFT) calculations by determining the host–guest interaction energy (Ehost–guest) with a nitrobenzene (NB)≫p‐xylene (p‐xy)≫o‐dichlorobenzene (o‐DCB) trend (i. e., from 44 to 25 kcal mol−1), assessing the XRD outcomes. Combining SC‐XRD, DFT and solid‐state 13C NMR, the exceptional stability of the M12L8 cages, together with the guest exchange/release properties were rationalized by considering the presence of mechanical bonds (efficient π–π interactions) and by the pyridine's rotor‐like behaviour (with 3 kcal mol−1 rotational energy barrier). The structure–function properties of M12L8 makes 1 a potential candidate in the field of molecular sensors.
Funder
Ministero dell’Istruzione, dell’Università e della Ricerca
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
1 articles.
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