Tetrazole and Oxadiazole Derivatives as Thermally Activated Delayed Fluorescence Emitters

Author:

Leonhardt Céline1ORCID,Mauri Anna2,Garin Idoia3,Rosemann Nils W.3ORCID,Wenzel Wolfgang2ORCID,Lemmer Uli3ORCID,Kozlowska Mariana2ORCID,Bräse Stefan14ORCID

Affiliation:

1. Institute of Organic Chemistry Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany

2. Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany

3. Light Technology Institute Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany

4. Institute of Biological and Chemical Systems – IBCS-FMS Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany

Abstract

AbstractOrganic light‐emitting diodes (OLEDs) are promising lighting solutions for sustainability and energy efficiency. Incorporating thermally activated delayed fluorescence (TADF) molecules enables OLEDs to achieve internal quantum efficiency (IQE), in principle, up to 100 %; therefore, new classes of promising TADF emitters and modifications of existing ones are sought after. This study explores the TADF emission properties of six designed TADF emitters, examining their photophysical responses using experimental and theoretical methods. The design strategy involves creating six distinct types of a donor‐acceptor (D−A) system, where tert‐butylcarbazoles are used as donors, while the acceptor component incorporates three different functional groups: nitrile, tetrazole and oxadiazole, with varying electron‐withdrawing character. Additionally, the donor‐acceptor distance is adjusted using a phenylene spacer, and its influence on TADF functionality is examined. The clear dependency of an additional spacer, inhibiting TADF, could be revealed. Emitters with a direct donor‐acceptor connection are demonstrated to exhibit TADF moderate emissive behavior. The analysis emphasizes the impact of charge transfer, singlet‐triplet energy gaps (ΔEST), and other microscopic parameters on photophysical rates, permitting TADF. Among the emitters, TCz‐CN shows optimal performance as a blue‐green emitter with an 88 % photoluminescence quantum yield (PLQY) and fast rate of reversible intersystem crossing of 2×106 s−1 and 1×107 s−1, obtained from time‐resolved photoluminescence (TRPL) experiment in PMMA matrix and quantum mechanical calculations, respectively. This comprehensive exploration identifies molecular bases of superior TADF emitters and provides insights for future designs, advancing the optimization of TADF properties in OLEDs.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

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