Facile Synthesis of High‐Entropy Alloy Nanowires for Electrocatalytic Alcohol Oxidation

Author:

Ling Xinyi1,Ao Yunyun1,Zheng Jinyu1,Han Min2,Xu Dongdong13

Affiliation:

1. Jiangsu Key Laboratory of New Power Batteries School of Chemistry and Materials Science Nanjing Normal University Nanjing 210023 P. R. China

2. Fujian Cross Strait Institute of Flexible Electronics (Future Technology) Fujian Normal University Fuzhou 350117 P. R. China

3. State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210023 P. R. China

Abstract

AbstractConsidering the structural and compositional advantages of high‐entropy alloy (HEA) as high‐efficient electrocatalysts, we here present a facile method to prepare high‐entropy alloy nanowires with seven elements in an aqueous solution. The as‐synthesized PdPtCuAgAuPbCo nanowires possess dispersed one‐dimensional morphology and exhibit enhanced electrocatalytic performance with the mass activity of 9.9 A mgPd+Pt−1 toward ethanol electrooxidation. The HEA nanowires also perform superior stability, resistance to CO poisoning, and good electrocatalytic activities toward other alcohols (e. g., ethylene glycol and methanol) oxidation. The synthesis strategy is easy to operate with low cost and has wide application prospects for preparing desired electrocatalysts for fuel cells.

Publisher

Wiley

Subject

General Chemistry

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