Highly Specific Sulfadiazine Detection Using a Two‐Dimensional Europium‐Organic Coordination Polymer

Author:

Min Hui1ORCID,Zhu Zhuo‐hang1,Min Yu‐jiao1,Yao Binling1,Cheng Peng2ORCID

Affiliation:

1. Hubei Key Laboratory of Pollutant Analysis & Reuse Technology College of Chemistry and Chemical Engineering Hubei Normal University Huangshi Hubei province 435002 P. R. China

2. Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry Frontiers Science Center for New Organic Matter Haihe Laboratory of Sustainable Chemical Transformations (Tianjin) College of Chemistry Nankai University Tianjin 300071 P. R. China

Abstract

AbstractSulfadiazine (SFZ) is an inexpensive large‐consumption antibiotic used for treat bacterial infections but an excess of residues in food can be harmful. Fast and specific luminescence detection of SFZ is highly challenging because of the interference of structurally similar antibiotics. In this work, we develop a two‐dimensional europium‐organic coordination polymer with excellent luminescence and water stability for highly specific detection of SFZ in the range of 0–0.2 mM. Structural analysis shows that the high stability of coordination polymer is due to the high coordination number of europium ion and the special chelating coordination structure of ligand. The experiment results revealed that the high selectivity and effectively luminescence quenched behaviour of coordination polymer toward SFZ is caused by highly efficient inner filter effect.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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