Observation of a Long‐lived Electronic Coherence Modulated by Vibrational Dynamics in Molecular Nd3+‐Complexes at Room Temperature

Author:

Ghosh Jayanta1ORCID,Gheibi Mirali1,Kalas Tillmann1,Sarpe Cristian1,Zielinski Bastian1,Ciobotea Ramela1,Burghard Morscher Christoph1,Koehne Ingo2,Pietschnig Rudolf2ORCID,Senftleben Arne1ORCID,Baumert Thomas1ORCID,Braun Hendrike1ORCID

Affiliation:

1. Institute of Physics and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT) University of Kassel Heinrich-Plett-Str. 40 34132 Kassel Germany

2. Institute of Chemistry and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT) University of Kassel Heinrich-Plett-Str. 40 34132 Kassel Germany

Abstract

AbstractTemporally delayed, phase‐locked coherent pairs of near IR femtosecond laser pulses were employed to study electronic coherences in molecular Nd3+‐complexes at room temperature. Dissolved and solid complexes were studied under a confocal microscope set‐up with fluorescence detection. The observed electronic coherence on a few hundred femtoseconds time scale is modulated by additional coherent wave packet dynamics, which we attribute mainly to be vibrational in nature. In future, the complexes may serve as prototypes for possible applications in quantum information technology.

Publisher

Wiley

Subject

Physical and Theoretical Chemistry,Atomic and Molecular Physics, and Optics

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