Visible‐Light‐Mediated Synthesis of Aryl Ketones and Aldehydes from <i>N</i>‐(acyloxy)phthalimides Esters-Reference-Cited by-同舟云学术

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Visible‐Light‐Mediated Synthesis of Aryl Ketones and Aldehydes from N‐(acyloxy)phthalimides Esters

Published:2024-02-06 Issue:4 Volume:13 Page:
ISSN:2193-5807
Container-title:Asian Journal of Organic Chemistry
language:en
Short-container-title:Asian J Org Chem

Author:

Ding Di¹,Wan Ruiying²,Qi Yuchen¹²,Gong Lili²,Zhang Zixuan¹,Guan Haixing²^ORCID,Li Wei¹,Zhu Qingjun³

Affiliation:

1. College of Pharmacy Shandong University of Traditional Chinese Medicine Jinan 250355 P. R. of China

2. Experimental Center Shandong Provincial Key Laboratory of Traditional Chinese Medicine Key Laboratory of Traditional Chinese Medicine Classical Theory Ministry of Education Shandong University of Traditional Chinese Medicine Jinan 250355 P. R. of China

3. Innovative Institute of Chinese Medicine and Pharmacy Shandong University of Traditional Chinese Medicine Jinan 250355 P. R. of China

Abstract

AbstractA visible‐light‐mediated decarboxylative oxidation of benzylic redox active esters is described. A diverse array of aromatic ketones or aldehydes could be achieved (15 examples) from secondary or primary aliphatic carboxylic acids. A mechanism involving resonance transformation in the presence of Cs2CO3 is proposed.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ajoc.202400008

Reference57 articles.

1. The Barton ester free-radical reaction: a brief review of applications

2. Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

4. Photoredox-Catalysed Decarboxylative Alkylation of N-Heteroarenes with N -(Acyloxy)phthalimides

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