Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3 )2 ]3 }−
Author:
Affiliation:
1. Department of Chemistry; University of California, Irvine; 1102 Natural Sciences II Irvine CA 92697-2025 USA
2. Sandia National Laboratories; Advanced Materials Laboratory; 1001 University Blvd. SE Albuquerque NM 87106 USA
Publisher
Wiley
Subject
General Chemistry,Catalysis
Reference63 articles.
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2. Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution
3. Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins Based on the Nondegenerate Exchange of Alkyl Groups and σ-Bond Metathesis at Scandium
4. Synthesis and Characterization of Scandium Silyl Complexes of the Type Cp*2ScSiHRR‘. σ-Bond Metathesis Reactions and Catalytic Dehydrogenative Silation of Hydrocarbons
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