Affiliation:
1. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University Chengdu Sichuan 610064 China
Abstract
Comprehensive SummaryAlternative synthetic routes toward the tricyclic core of lindenane sesquiterpenoid are presented herein. The route A features an asymmetric organocatalysis enabling desymmetric silylation of diol to establish the desired tertiary alcohol, while the route B consists of an acetate ring opening of chiral epoxy moiety. The common intermediate (16) in both routes can give rise to the core of lindenane sesquiterpenoid via an intramolecular cyclopropanation.
Cited by
3 articles.
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