Recent Advances in Enantioselective Reactions of Terminal Unactivated Alkenes

Author:

Guo Qihang12,Shen Xuzhong1,Lu Zhan13

Affiliation:

1. Center of Chemistry for Frontier Technologies, Department of Chemistry Zhejiang University Hangzhou Zhejiang 310058 China

2. ZJU‐Hangzhou Global Scientific and Technological Innovation Center Hangzhou Zhejiang 311215 China

3. College of Chemistry, Zhengzhou University Zhengzhou Henan 450001 China

Abstract

Comprehensive Summaryα‐Olefins as aliphatic terminal alkenes could be obtained easily from numerous contemporary synthetic reactions as well as petrochemical industry, and also found in natural products. Compared to the alkenes attaching the directing groups or activating group, the catalytic asymmetric reaction of unactivated terminal alkenes presents great challenges due to the weak electron effect and small steric hindrance effect. This review mainly summarizes the latest progress of the asymmetric reaction of unactivated terminal olefins since 2016. Key Scientistsimage

Publisher

Wiley

Subject

General Chemistry

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