Affiliation:
1. State Key Laboratory of Coordination Chemistry, Chemistry and Biomedicine Innovation Center of Nanjing University, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering Nanjing University Nanjing Jiangsu 210023 China
Abstract
Comprehensive SummaryNitroanilines are important building blocks in pharmaceuticals, materials and dyes. Nitration methods for anilines under mild conditions are highly desired. Herein, we report a photochemical method for the nitration of anilines bearing various protecting groups by 5‐methyl‐1,4‐dinitroimidazole as a new type of nitro source. This method is light‐controlled and proceeds under mild reaction conditions with high efficiency. Fmoc‐, Ts‐ and alkyl‐protected anilines are all well nitrated with good functional group tolerance.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Cited by
4 articles.
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