Substrate‐Dependent Divergent Oxyamination of beta‐Tetralones Enabling Modular Synthesis of 2‐Amino‐para‐Iminonaphthoquinones and 4‐Amino‐1,2‐Naphthoquinone Derivatives

Author:

Wang Shuowen1,Li Rong1,Huang Huawen1ORCID,Mao Guojiang2,Shao Wen1,Deng Guo‐Jun1ORCID

Affiliation:

1. Key Laboratory for Green Organic Synthesis and Application of Hunan Province Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education College of Chemistry Xiangtan University Xiangtan 411105 China

2. Department School of Chemistry and Chemical Engineering Henan Normal University Xinxiang 453007 China

Abstract

AbstractA regioselective synthesis of 2‐amino‐para‐iminonaphthoquinones and 4‐amino‐1,2‐naphthoquinones was described via the substrate‐dependent divergent multi‐functionalization of β‐tetralone with primary and secondary amines under metal‐free conditions. This developed strategy features extremely green and mild conditions (O2 as oxidant, ethanol as solvent under ambient temperature), broad substrate scope, and various pharmaceutical derivatizations.magnified image

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3