Affiliation:
1. Inner Mongolia Key Laboratory of the Natural Products Chemistry and Functional Molecular Synthesis College of Chemistry and Materials Science Inner Mongolia Minzu University Tongliao 028000 People's Republic of China
2. Jiangsu Collaborative Innovation Center of Biomedical Functional Materials Jiangsu Key Laboratory of Biofunctional Materials Key Laboratory of Applied Photochemistry School of Chemistry and Materials Science Nanjing Normal University Nanjing 210023 People's Republic of China
Abstract
AbstractWe present here an iron‐catalyzed oxidative Csp3−Csp3 bond cleavage of unstrained tertiary alkyl aromatics to provide a range of synthetically useful arylketones even with H2O2 as the oxidant. This method is operationally simple, scalable, and eco‐friendly, as well as suitable for the late‐stage oxidation of complex molecules bearing hydroxy groups, making it a valuable tool in organic synthesis.
Funder
National Natural Science Foundation of China
Cited by
2 articles.
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