Visualizing Circularly Polarized Long Afterglow for Information Security

Author:

Zhao Shanshan1,Li Guangen1,Guo Qi1,Wang Yaxin1,Zhang Mingjiang1,Zhou Yajie1,Jin Shan2,Zhu Manzhou2,Zhuang Taotao1ORCID

Affiliation:

1. Division of Nanomaterials and Chemistry Hefei National Research Center for Physical Sciences at the Microscale Department of Chemistry University of Science and Technology of China Hefei 230026 P. R. China

2. Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education Department of Chemistry, and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials Anhui University Anhui Province Hefei Anhui 230601 P. R. China

Abstract

AbstractCreating security materials that carry distinct information with numerous optical characteristics enables enhanced anticounterfeiting levels to deter forgery ranging from currencies to pharmaceuticals. Circularly polarized long afterglow (CPLA) has attracted extensive attention in anticounterfeiting owing to its multiple and unusual optical properties (i.e., long afterglow and circular polarization), introducing intensity variation into the time dimension. However, constructing a visualized CPLA—meeting the requirements toward practical applications—is still a challenge. Here, a cementation‐coupling strategy is designed to combine chiral photonic membranes with phosphor films for building full‐colored CPLA architectures. The CPLA systems achieve desired performance with a largest afterglow dissymmetry value (gCPLA) of −0.67 and a longest visualization time (tvis) of 40 min simultaneously, satisfying practical demands for information security. As‐prepared CPLA materials are further patterned to work as optical labels in security fields. The resulting multidimensional variations in both time and intensity increase the complexity of information encryption, offering potentials for advanced security technologies.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Wiley

Subject

Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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