Understanding the Inherent Properties of Vapor Phase Poly (3,4 – Ethylenedioxythiophene) Deposited Stretchable Conducting Films

Author:

Sethumadhavan Vithyasaahar1ORCID,Switalska Eliza2ORCID,Shahbazi Mahboobeh2,Li Yong3,Zuber Kamil2ORCID,Wang Tony4ORCID,Alarco Jose1,Evans Drew R.2ORCID,Sonar Prashant1

Affiliation:

1. School of Chemistry and Physics & Centre for Material Science Queensland University of Technology Brisbane QLD 4000 Australia

2. Future Industries Institute University of South Australia Mawson Lakes SA 5095 Australia

3. CSIRO Energy Centre Mayfield West NSW 2304 Australia

4. Central Analytical Research Facility (CARF) Queensland University of Technology Brisbane QLD 4000 Australia

Abstract

AbstractStretchable conducting films are a prime necessity for future stretchable and wearable electronics. In this work, highly conducting poly(3,4 ethylenedioxythiophene):Tosylate (PEDOT:Tos) films are deposited on extremely stretchable styrene‐ethylene‐butylene‐styrene (SEBS) substrates via vapor phase polymerization (VPP) and their inherent properties are systematically studied. The charge transport and electrical properties of VPP PEDOT:Tos stretchable films are measured from room temperature down to the low temperature of 5 K. Interestingly, the mechanical properties of the stretchable substrate lead to buckling of the PEDOT:Tos that affect the electrical conductivity but not the charge carrier mobility, optical, and structural properties. The VPP PEDOT:Tos on the stretchable SEBS substrate show a semiconducting behavior as electrical resistance is enhanced upon cooling from room temperature to 5 K. Such kind of stretchable conducting films can be used for stretchable transistors, wearable sensing, energy storage, and electrochromic applications.

Funder

Australian Research Council

Commonwealth Scientific and Industrial Research Organisation

Publisher

Wiley

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