Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System

Author:

Senkovska Irena1ORCID,Bon Volodymyr1ORCID,Abylgazina Leila1ORCID,Mendt Matthias2ORCID,Berger Jan3ORCID,Kieslich Gregor3ORCID,Petkov Petko4ORCID,Luiz Fiorio Jhonatan5ORCID,Joswig Jan‐Ole5ORCID,Heine Thomas567ORCID,Schaper Larissa8ORCID,Bachetzky Christopher9ORCID,Schmid Rochus8ORCID,Fischer Roland A.3ORCID,Pöppl Andreas2ORCID,Brunner Eike9ORCID,Kaskel Stefan1ORCID

Affiliation:

1. Chair of Inorganic Chemistry I Technische Universität Dresden Bergstrasse 66 01069 Dresden Germany) E-mal

2. Felix Bloch Institute for Solid State Physics Universität Leipzig Linnéstraße 5 04103 Leipzig Germany

3. Inorganic and Metal-Organic Chemistry Technical University of Munich Lichtenbergstraße 4 85748 Garching Germany

4. Faculty of Chemistry and Pharmacy Sofia University 1 James Bourchier Blvd. 1164 Sofia Bulgaria

5. Chair of Theoretical Chemistry Technische Universität Dresden Bergstraße 66c 01069 Dresden Germany

6. Helmholtz-Zentrum Dresden-Rossendorf, Forschungsstelle Leipzig Permoserstraße 15 04318 Leipzig Germany

7. Department of Chemistry Yonsei University Seodaemun-gu, Seoul 120-749 Republic of Korea

8. Computational Materials Chemistry Group Faculty of Chemistry and Biochemistry Ruhr-Universität Bochum Bochum Germany

9. Chair of Bioanalytical Chemistry Technische Universität Dresden Bergstraße 66 01069 Dresden Germany

Abstract

AbstractFlexible porous frameworks are at the forefront of materials research. A unique feature is their ability to open and close their pores in an adaptive manner induced by chemical and physical stimuli. Such enzyme‐like selective recognition offers a wide range of functions ranging from gas storage and separation to sensing, actuation, mechanical energy storage and catalysis. However, the factors affecting switchability are poorly understood. In particular, the role of building blocks, as well as secondary factors (crystal size, defects, cooperativity) and the role of host–guest interactions, profit from systematic investigations of an idealized model by advanced analytical techniques and simulations. The review describes an integrated approach targeting the deliberate design of pillared layer metal–organic frameworks as idealized model materials for the analysis of critical factors affecting framework dynamics and summarizes the resulting progress in their understanding and application.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

Subject

General Medicine

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