Stellated cuboctahedron of Fe<sup>III</sup>-Reference-Cited by-同舟云学术

Stellated cuboctahedron of Fe^III

Published:2024-08 Issue:37 Volume:136 Page:
ISSN:0044-8249
Container-title:Angewandte Chemie
language:en
Short-container-title:Angewandte Chemie

Author:

Wilson Lucinda R. B.¹^ORCID,Canaj Angelos B.¹^ORCID,Cutler Daniel J.²^ORCID,McCormick McPherson Laura J.³^ORCID,Coles Simon J.³^ORCID,Nojiri Hiroyuki²^ORCID,Evangelisti Marco⁴^ORCID,Schnack Jürgen⁵^ORCID,Dalgarno Scott J.⁶^ORCID,Brechin Euan K.¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry The University of Edinburgh David Brewster Road Edinburgh EH9 3FJ Scotland UK

2. Institute for Materials Research Tohoku University Sendai 980-8577 Japan

3. EPSRC National Crystallography Service School of Chemistry University of Southampton Highfield Southampton SO17 1BJ England UK

4. Instituto de Nanociencia y Materiales de Aragón (INMA) CSIC & Universidad de Zaragoza 50009 Zaragoza Spain

5. Fakultät für Physik Universitat Bielefeld Postfach 100131 D-33501 Bielefeld Germany

6. Institute of Chemical Sciences Heriot-Watt University Riccarton Edinburgh EH14 4AS Scotland UK

Abstract

AbstractThe solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied‐field changes lower than 3 T.

Funder

Leverhulme Trust

Japan Society for the Promotion of Science London

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.202405666

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