Liquid‐Liquid Extraction of Caproic and Caprylic Acid: Solvent Properties and pH

Author:

Yuan Bomin1ORCID,Braune Maria1ORCID,Gröngröft Arne1

Affiliation:

1. DBFZ Deutsches Biomasseforschungszentrum gemeinnützige GmbH Biorefineries Department Torgauer Straße 116 04347 Leipzig Germany

Abstract

AbstractCaproic acid (C6) and caprylic acid (C8) can be produced during anaerobic fermentation via chain elongation processes. This study focused on the selective recovery of C6 and C8 from a fermentation broth with liquid‐liquid extraction. Eight solvents, including alcohols, esters, an organophosphorus compound, and an amine, were evaluated based on their extraction efficiency and selectivity for C6 and C8. The highest extraction efficiency of C6 (46 %) and C8 (93 %) at pH 6.0 was achieved by 1‐octanol. Oleyl alcohol, 1‐decanol, and 1‐octanol had the highest selectivity for C6 and C8.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Wiley

Subject

Industrial and Manufacturing Engineering,General Chemical Engineering,General Chemistry

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