Development of green polystyrene composites using Citrus sinensis biochar filler

Author:

Adeniyi Adewale George1ORCID,Abdulkareem Sulyman Age1,Iwuozor Kingsley O.2,Abd‐Elkader Omar H.3,Amoloye Mubarak A.1,Emenike Ebuka Chizitere2,Omonayin Ebenezer O.1,Oyekunle Ifeoluwa Peter4,Ezzat Abdelrahman O.5

Affiliation:

1. Department of Chemical Engineering Faculty of Engineering and Technology University of Ilorin Ilorin Nigeria

2. Department of Pure and Industrial Chemistry Nnamdi Azikiwe University Awka Nigeria

3. Department of Physics and Astronomy College of Science King Saud University Riyadh Saudi Arabia

4. Department of Chemistry and Biochemistry Florida State University Tallahassee Florida USA

5. Department of Chemistry College of Sciences King Saud University Riyadh Saudi Arabia

Abstract

AbstractThis research explored the characteristics of polymer composites reinforced with orange peel biochar. The composites were created using the hand lay‐up method with different filler ratios, cured at ambient temperature, and analyzed with various analytical techniques, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy, and energy dispersive X‐ray spectroscopy (EDX). SEM images showed that roughness increased with higher filler percentages. FTIR analysis detected functional groups like OH, COOH, and aromatic compounds in the composites, primarily inheriting these groups from the resin. Elemental analysis using EDX indicated that the composites contained carbon, oxygen, silicon, aluminum, and potassium. Among these elements, only the carbon concentration demonstrated a linear increase with rising filler levels, with the composite containing 40% biochar achieving the highest carbon content at 84%. Hardness testing showed that the physical strength of the composites increased as the polystyrene resin matrix was reinforced, with the 40% biochar composite exhibiting a maximum hardness value of 296 N. These results indicate that adding biochar not only enhanced the properties of polystyrene‐based composites but also reduced their environmental impact.

Funder

King Saud University

Publisher

Wiley

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