Affiliation:
1. Key Laboratory of Photonic Materials and Devices Physics for Oceanic Applications Ministry of Industry and Information Technology of China College of Physics and Optoelectronic Engineering Harbin Engineering University Harbin 150001 China
2. Key Laboratory of In‐Fiber Integrated Optics of Ministry of Education College of Physics and Optoelectronic Engineering Harbin Engineering University Harbin 150001 China
3. Laboratory of Superlight Materials and Surface Technology of Ministry of Education Harbin Engineering University Harbin 150001 China
Abstract
AbstractMagnesium–lithium‐ion hybrid batteries (MLIBs) have gained significant attention since the combination of a dendrite‐free and low‐cost magnesium anode with lithium‐ion storage cathodes. However, the lack of high‐performance cathodes has severely hindered their development, limited by the lower operating voltages of electrolytes. Herein, vanadium molybdenum disulfide nanosheets anchoring on flexible carbon cloth (VMS@CC) are constructed as high‐performance cathodes for MLIBs, which inherit the electrochemical properties of high‐voltage VS2 and high‐capacity MoS2, simultaneously. By adjusting the V and Mo atomic ratio, the VMS@CC cathode for MLIBs delivers a record maximum energy density of 275.5 Wh kg−1 with a high working voltage of 1.07 V at 50 mA g−1. Meanwhile, under the synergistic effects of the conductive carbon cloth matrix, abundant hetero‐interfaces and defects, as well as expanded interlayer spacing, the VMS@CC cathode displays superior rate capability and long‐term cycling stability. Ex situ analyses demonstrate the VMS nanosheets cathode exhibits a Li+/Mg2+ co‐insertion/extraction mechanism in MLIBs, following the in situ insertion of organic species in the hybrid electrolyte during the aging process. The fabricated flexible cathode herein provides a new insight into the construction of high‐energy density cathodes for MLIBs.
Funder
Fundamental Research Funds for the Central Universities
China Scholarship Council
Natural Science Foundation of Heilongjiang Province