Affiliation:
1. College of Materials Science and Engineering Sichuan University Chengdu 610065 P. R. China
2. Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China Chengdu 610054 P. R. China
3. Engineering Research Center of Alternative Energy Materials & Devices Ministry of Education Chengdu 610065 P. R. China
Abstract
AbstractSolid‐state anion exchange method is easy to handle and beneficial to improve stability of CsPbX3 (X = Cl, Br, I) perovskites nanocrystals (NCs) with respect to anion exchange in liquid phase. However, the corresponding exchange rate is rather slow due to the limited diffusion rate of anions from solid phases, resulting in mixed‐halide perovskite NCs. Herein, a fast and reversible post‐synthetic quasi‐solid‐state anion exchange method in CsPbX3 NCs with inorganic potassium halide KX salts/polyvinylpyrrolidone (PVP) thin film is firstly reported. Original morphology of the exchanged NCs is well‐preserved for all samples. Complete anion exchange from Br− to Cl− or I− is successfully achieved in CsPbX3 NCs within ≈20 min through possible vacancies‐assisted ion exchange mechanism, under ambient conditions and vice versa. Particularly, Br−‐exchanged CsPbCl3 and CsPbI3 NCs exhibit improved optical properties. Encouraged by the attractive fluorescence and persistent luminescence as well as good stability of the resulted CsPbX3 NCs, an effective dual‐mode information storage–reading application is demonstrated. It is believed that this method can open a new avenue for the synthesis of other direct‐synthesis challenging quantum‐confined perovskite NCs/nanoplates/nanodisks or CsSnX3 NCs/thin film and provide an opportunity for advanced information storage compatible for practical applications.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Sichuan Province Science and Technology Support Program
Subject
Biomaterials,Biotechnology,General Materials Science,General Chemistry