A facile synthesis and luminescence properties of CeF3:Tb3+ via polyol method

Author:

Yue Dan1ORCID,Zhang Lisha12,Wang Haojie1,Liu Deri1,Yang Xiaotong1,Lu Zhiqiang1,Li Mingjia1,Li Weidong1,Chen Dong1,Wang Zhenling1

Affiliation:

1. College of Material Engineering Henan International Joint Laboratory of Rare Earth Composite Materials Henan University of Engineering Zhengzhou 451191 China

2. College of Chemistry Zhengzhou University Zhengzhou 450001 China

Abstract

AbstractSugar gourd shaped CeF3:Tb3+ has been successfully synthesized by polyol method. The phase, morphology and fluorescent properties of CeF3:Tb3+ were characterized by X‐ray diffraction (XRD), transmission electron microscopy (TEM), infrared spectroscopy (IR) and photoluminescence (PL) spectra, respectively. It can be seen that the volume changes of giethylene glycol (DEG) and H2O content did not affect the phase structure of CeF3:Tb3+. The emission spectrum of CeF3:Tb3+ shows the characteristic emissions of Tb3+ ion, indicating that an energy transfer from Ce3+ to Tb3+ occurs in CeF3:Tb3+, and the decay time of CeF3:Tb3+ was not affected by the change of DEG content.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Inorganic Chemistry

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