Affiliation:
1. Section for Solid State and Theoretical Inorganic Chemistry Institute of Inorganic Chemistry Eberhard Karls University Tübingen Auf der Morgenstelle18 D-72076 Tübingen Germany
Abstract
AbstractThe new binary metal carbodiimide La2S2(CN2) was synthesized via a solid‐state metathesis reaction. The crystal structure was solved and refined on the basis of single‐crystal X‐ray diffraction data with space group C2/m. The structure is represented by a layered arrangement, based on alternating layers of lanthanum, sulfide, and carbodiimide units. A close resemblance of the structure with that of La2O2C2 is discussed, as well as the less‐common coordination number seven of the lanthanum atom.
Funder
Deutsche Forschungsgemeinschaft