Inorganic metal oxide‐reinforced polymer‐based flexible inorganic nanocomposite for UV shielding applications

Abstract

AbstractThis investigation reveals the successful incorporation of strontium‐doped thorium oxide (SrThO3) NPs into polyvinyl alcohol (PVA) polymer nanocomposites. The fabrication process of these PVA nanocomposites entails utilizing varying amounts (0.5, 1.0, 2.0, and 4.0 wt%) of SrThO3 nanofillers through a straightforward solution casting technique. The microstructure and overall structure of the resulting polymer nanocomposites were analyzed using powdered x‐ray diffraction for crystalline structure and Fourier transform infrared (FTIR) spectroscopy for molecular composition. The introduced SrThO3 nanofiller demonstrates a strong affinity for the hydroxyl groups present in the PVA polymer, a phenomenon validated through FTIR spectroscopy. In order to comprehend the impact of doping, the surface morphology of the PVA polymer nanocomposites underwent examination via scanning electron microscopy. The absorption and transmission of light were quantitatively assessed using UV–visible spectroscopy. The excitation and emission behaviors of electrons in both the PVA and SrThO3‐doped PVA nanocomposites were scrutinized through photoluminescence spectroscopy. Furthermore, the extent of UV light absorption was investigated by studying the degradation of methylene blue dye, a substance known for its sensitivity to UV light. Results indicate that the intentional incorporation of SrThO3 NPs significantly enhances UV stability.