Affiliation:
1. Department of Chemical Technologies of Polymer Composite Paints and Coatings Mendeleev University of Chemical Technology Moscow Russia
2. Laboratory of structural and morphological research A. N. Frumkin Institute of Physical Chemistry and electrochemistry of Russian Academy of Sciences Moscow Russia
Abstract
AbstractA material capable of curing due to UV irradiation based on an alkyd oligomer and oligoorganosilsesquioxanes (OOSs) with functional thiol groups was obtained. Using microinterferometry, it was shown that the alkyd oligomer and OOS are completely compatible (mutually soluble). The resulting alkyd‐siloxane composition was cured under the action of UV irradiation due to reaction between double bonds of alkyd oligomer and thiol‐groups of silsesquioxane oligomer. The curing reaction takes 5 min with formation of coating, containing 99% of gel fraction, which is in 30 times faster in comparison with the classical method of alkyd curing in the presence of siccatives. The hydrophobicity of alkyd‐siloxane coatings also increases and varies depending on the content of OOS. The introduction of 50% OOS into the alkyd oligomer makes it possible to increase the water contact angle by 10° relative to the coating based on pure alkyd. A similar dependence is observed when studying the thermal stability of coatings. Thus, even with the introduction of 10% OOS into alkyd oligomer, the temperature at which a loss of 50% of mass occurs increases by 24°C relative to coatings based on a pure alkyd oligomer.