Ti3C2/Ni/Sm‐Based Screen‐Printed‐Electrode for the ECL Detection of Hydrogen Peroxide as a Milk Preservative

Author:

Arshian Shayesteh1,Firoozbakhtian Ali2,Salehnia Foad3,Naghavi Sheikholeslami Mahsa1,Hamidipanah Yalda1,Gilnezhad Javad1,Reza Ganjali Mohammad1,Hosseini Morteza2ORCID

Affiliation:

1. Center of Excellence in Electrochemistry School of Chemistry College of Science University of Tehran 1439817435 Tehran Iran

2. Nanobiosensors Lab Department of Life Science Engineering Faculty of New Sciences & Technologies University of Tehran 1439817435 Tehran Iran

3. Departament d'Enginyeria Electrònica Escola Tècnica Superior d'Enginyeria Universitat Rovira i Virgili Avda. Països Catalans 26 43007 Tarragona Spain

Abstract

AbstractHydrogen peroxide is a widely used agent in the food industry for its sterilization, packaging, and transportation capabilities. However, its excessive concentration can lead to adverse health effects, especially in gastrointestinal conditions. As a result, it is crucial to detect its presence in food products, particularly milk. To address this need, we have developed a state‐of‐the‐art MXene‐based ECL system that can detect low‐concentration hydrogen peroxide levels with high sensitivity and accuracy. Our system incorporates 2D MXene structures, which not only enhance electrode conductivity but also form a complex with Ni/Sm‐LDH (layered double hydroxide) that enables detection across a broad linear range of 0.05–2 ppm in real samples. Furthermore, we have successfully lowered the detection limit to an impressive 0.005 ppm. With this innovative approach, we can ensure the safety and quality of food products, making it a significant breakthrough in the food industry.

Funder

Agence Universitaire de la Francophonie

University of Tehran

Publisher

Wiley

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