Intermolecular Interactions of Binary Mixtures Comprising 2‐Benzylaminoethanol with Alcohols (C<sub>1</sub>−C<sub>3</sub>) at Different Temperatures: Experiments and Modelling-Reference-Cited by-同舟云学术

Intermolecular Interactions of Binary Mixtures Comprising 2‐Benzylaminoethanol with Alcohols (C₁−C₃) at Different Temperatures: Experiments and Modelling

Published:2024-02-22 Issue:8 Volume:9 Page:
ISSN:2365-6549
Container-title:ChemistrySelect
language:en
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Author:

Belabbaci Aouicha¹,Ayad Amal¹,Negadi Amina¹,Hernández Ariel²,Kabane Bakusele³,Bahadur Indra⁴^ORCID,Mohammad Faruq⁵,Mokbel Ilham⁶⁷,Negadi Latifa¹⁸^ORCID

Affiliation:

1. LATA2M, Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire University of Tlemcen, Post Office Box 119 Tlemcen 13000 Algeria

2. Departamento de Ingeniería Industrial, Facultad de Ingeniería Universidad Católica de la Santísima Concepción Alonso de Ribera 2850 Concepción 11300 Chile

3. Department of Physical Chemistry laboratories, Faculty of Applied Sciences Durban University of Technology Durban 4001 South Africa

4. Department of North-West University (Mafikeng Campus) Private Bag X2046 Mmabatho 2735 South Africa

5. Department of Chemistry, College of Science King Saud University P.O. Box 2455 Riyadh Kingdom of Saudi Arabia 11451

6. LMI-UMR 5615, Laboratoire Multimatériaux et Interfaces Université Claude Bernard Lyon1, 43, Bd du 11 Novembre 1918 69622 Villeurbanne Cedex France

7. Université de Saint Etienne, Jean Monnet F-42023 Saint Etienne France

8. Thermodynamics Research Unit, School of Engineering University of KwaZulu-Natal, Howard College Campus King George V Avenue 4041 Durban South Africa

Abstract

AbstractThis manuscript represents the physical quantities comprising the densities, speed of sound and refractive indices for the binary mixtures involving [2‐Benzylaminoethanol (BAE) with methanol, ethanol, 1‐propanol, or 2‐propanol] over a molar composition (xBAE=0–1). The measurements were conducted with the use of Anton Paar densimeter (DSA 5000 M) operated at different temperatures, T=(293.15–323.15) K and at atmospheric pressure. The intermolecular interactions occurring between the prepared binary mixtures were interpreted by computing the excess properties including excess molar volumes ( ), isentropic compressibilities ( ), intermolecular free length ( ), specific acoustic impedance ( ), relative association ( , relaxation strength ( ), and Rao's molar sound function ( ). The Redlich‐Kister polynomial equation was utilized to fit the computed excess properties and PC‐SAFT EoS was utilized for modeling the measured densities. In addition, the Laplace mixing rule as well as the Nomoto's relation were utilized for the modeling of refractive indices and speed of sound, respectively. The experimental data was found in good agreement with the theoretical data for the measured properties.

Publisher

Wiley

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