Synthesis and Application of New Benzophenone Photoinitiators

Author:

Feng Chao1,Wang Qin Lin1,Liu Feng12ORCID,Zhang Bianxiang1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering Shanxi University Taiyuan 030006 China

2. Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China

Abstract

AbstractA series of new benzophenone derivatives were synthesized by the esterification reaction of hydroxy‐benzophenone and acyl chloride or sulfonyl chloride. All the compounds were characterization by NMR and MS spectroscopy technology. The resulting products exhibited efficient UV light absorption in the range of 225–325 nm, leading to excellent photoinitiating effects as photoinitiators in light‐cured coatings. The cured film showed comparable mechanical performance with the commercial product. Moreover, we discussed the photoinitiation mechanism of the new benzophenone derivatives, which would promote the further development of novel photoinitiators for industry application.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry

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