Synthesis of 1‐phenyl‐3‐(quinolin‐8‐ylamino)prop‐2‐en‐1‐one and analysis of its structure by X‐ray crystallography, NMR, UV‐Vis spectroscopy and DFT calculations-Reference-Cited by-同舟云学术

Synthesis of 1‐phenyl‐3‐(quinolin‐8‐ylamino)prop‐2‐en‐1‐one and analysis of its structure by X‐ray crystallography, NMR, UV‐Vis spectroscopy and DFT calculations

Published:2024-02-21 Issue:8 Volume:9 Page:
ISSN:2365-6549
Container-title:ChemistrySelect
language:en
Short-container-title:ChemistrySelect

Author:

Volkov Michael Yu.¹^ORCID,Sharipova Alsu R.¹,Turanova Olga A.¹^ORCID,Gubaidullin Aidar T.²,Shaidullina Amina F.³,Savostina Ludmila I.¹³,Turanov Alexander N.¹

Affiliation:

1. Zavoisky Physical-Technical Institute FRC Kazan Scientific Center of RAS Kazan Sibirsky tract, 10/7 420029 Russia

2. Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center of RAS Kazan Arbuzov str. 8 420088 Russia

3. Institute of Physics Kazan Volga Region Federal University Kazan Kremlyovskaya str. 18 420008 Russia

Abstract

Abstract1‐phenyl‐3‐(quinolin‐8‐ylamino)prop‐2‐en‐1‐one was obtained by a two‐step synthesis. From X‐ray crystallography, NMR and UV‐vis spectra it follows that in the crystalline state and in solutions, regardless of the polarity of the solvent, 1‐phenyl‐3‐(quinolin‐8‐ylamino)prop‐2‐en‐1‐one exists in the ketone form of the cis‐isomer. DFT calculations confirmed that the cis‐isomer is the most energetically favorable among all its isomers.

Publisher

Wiley

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