Affiliation:
1. College of Bioscience and Resources Environment Beijing University of Agriculture Beijing P. R. China
2. Key Laboratory of Urban Agriculture In North China Ministry of Agriculture and Rural Affairs, P. R. China, Beijing University of Agriculture Beijing P. R. China
3. Total Component Analysis Laboratory Nutrichem Co., Ltd. Beijing P. R. China
Abstract
AbstractThe objective of this study was to develop a simple, rapid, and efficient pretreatment method using a supramolecular solvent as the extractant combined with high‐performance liquid chromatography‐ultraviolet to detect benzimidazole residues in environmental soil. The supramolecular solvent was composed of long‐chain alcohols, tetrahydrofuran, and water in proportion, showing excellent solubility and polarity range, so a supramolecular solvent microextraction method was established. The optimum method was identified by optimizing the types of long‐chain alcohols, the alcohol/tetrahydrofuran ratio, the pH, the amount of extractant, and the extraction time. The detection limits were 12.1–39.9 μg/kg with a relative standard deviation between 1.2% and 3.2% (n = 6). The recoveries ranged between 56.6% and 86.1%, and the linear relationship was good. The correlation coefficient (r2) was 0.9843 ‐ 0.9998. This method was then used to measure five benzimidazoles (thiabendazole, albendazole sulfone, ophendazole, albendazole, and fendazole) in soil samples.
Subject
Filtration and Separation,Analytical Chemistry
Reference26 articles.
1. Research progress on residue analysis of benzimidazoles (BMZs) fungicides;Chen W;J Zhejiang Agric Sci,2011
2. Profiling of benzimidazoles and related metabolites in pig serum based on SiO2@NiO solid-phase extraction combined precursor ion scan with high resolution orbitrap mass spectrometry
3. Rapid detection of benzimidazole pesticides in orange juice by LC‐MS;Yao YL;Chin J Health Lab Tech,2013
4. Research progress of toxicology of Carbendazim;Yu GC;Occ Health,2008
5. Review of methodology for the determination of benzimidazole residues in biological matrices;Martin D;J Chromatogr B,2007
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献