Tuning Microstructure of Mesophase Pitch Carbon Fiber by Altering the Carbonization Ramp Rate

Abstract

The microstructure of mesophase pitch carbon fibers (CFs) are tuned by varying ramp rates from 1 to 50 °C min−1 up to 1000 °C to study the effect of ramp rate on CFs’ microstructure, thermal and mechanical properties with the goal of offsetting the cost by decreasing cycle time. The ramp rates represent carbonization times ranging from 16.4 to 1.17 h, not including cool down. Differential scanning calorimetry, thermogravimetric analysis, and derivative thermogravimetry are used to investigate the impact ramp rate has on the thermal properties of mesophase pitch. It is found that lower ramp rates are endothermic in nature with a lower temperature onset and maximum weight loss. Higher ramp rates possess an exothermic nature with higher temperatures resulting in maximal weight loss over a smaller range of temperatures. Mechanical testing shows varying CF strengths and moduli dependent on ramp rate and an optimized process is developed to produce the strongest CF. Microstructural characterization revealed that faster ramp rates lead to smaller interplanar spacings and larger crystallites but possessed greater disorder.