Effect of the Precursor Metal Salt on the Oxygen Evolution Reaction for NiFe Oxide Materials

Author:

Zuber Axel1,Oikonomou Ilias M.23,Gannon Lee34,Chunin Igor34,Reith Lukas5,Can Belin1,Lounasvuori Mailis6,Schultz Thorsten78,Koch Norbert78,McGuinness Cormac34,Menezes Prashanth W.59,Nicolosi Valeria23,Browne Michelle P.1ORCID

Affiliation:

1. Helmholtz Young Investigator Group Electrocatalysis: Synthesis to Devices Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 14109 Berlin Germany

2. School of Chemistry Trinity College Dublin College Green Dublin 2 Ireland

3. CRANN and AMBER Research Centres Trinity College Dublin College Green Dublin 2 Ireland

4. School of Physics Trinity College Dublin College Green Dublin 2 Ireland

5. Department of Chemistry, Metalorganics, and Inorganic Materials Technische Universität Berlin Straße des 17 Juni 135, Sekr. C2 10623 Berlin Germany

6. Nanoscale Solid-Liquid Interfaces Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Albert-Einstein-Str. 15 12489 Berlin Germany

7. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Berlin 14109 Germany

8. Institut für Physik & IRIS Adlershof Humboldt-Universität zu Berlin Berlin 12489 Germany

9. Materials Chemistry Group for Thin Film Catalysis – CatLab Helmholtz-Zentrum Berlin für Materialien und Energie Albert-Einstein-Str. 15 12489 Berlin Germany

Abstract

AbstractBimetallic nickel‐iron based oxides are regarded as one of the most promising catalysts for the oxygen evolution reaction (OER). In this study, we show that the precursor metal salts can affect the OER activity of the resulting Ni/Fe oxide under the same hydrothermal synthesis conditions. Pure sulfate, pure nitrate and mixed sulfate/nitrate metal salts were used to fabricate NiFe based oxide materials and to study the importance of the precursor choice for the OER. The results show that the nature of the precursor used in the synthesis of the bimetallic nickel‐iron materials can influence different multi‐phase catalysts to form which effects the OER.

Funder

European Research Council

Science Foundation Ireland

Irish Research Council

Publisher

Wiley

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