Achieving Complete Conversion from Nickel Foam to Nickel Sulfide Foam for a Freestanding Hybrid‐Supercapacitor Electrode

Abstract

AbstractWe present a unique, one‐step, hydrothermal process to prepare nickel sulfide (Ni3S2) foam by a simple and direct conversion from nickel foam, which contributes both as a scaffold for the reaction and as reactant. The Ni3S2 foam exhibits remarkable mechanical stability, retaining the structural integrity of the foam and excellent crystallinity even after ultrasonication at 200 W for 30 mins. We document the transformation of the nickel foam template into a Ni3S2 foam, highlighting the role of synthesis duration on the phase evolution and unique morphology of Ni3S2. PXRD and SEM analyses reveal a complete transformation after 24 hours from the nickel foam to a pure Ni3S2 foam, which has a highly porous and interconnected ultra‐thin nanosheet architecture. This significantly enhances the surface area and provides many electrochemical reaction sites. In a three‐electrode cell, the capacity of the Ni3S2 foam electrode is 3.9 C cm−2 at 8 mA cm−2, which is higher than previous reports for Ni3S2. In a hybrid supercapacitor device, the Ni3S2 foam demonstrates significant increase in capacitance through 500 cycles and the capacitance plateaus after 2000 cycles. Even after 8500 continued charge‐discharge cycles, the device exhibits excellent cycle stability indicating improvement with age.