Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence-Reference-Cited by-同舟云学术

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Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence

Published:2024-05-13 Issue:16 Volume:16 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Chen Zheng‐Yu¹,Ji Xiao‐Ming¹,Wang Xue¹,Asgari Motahareh¹,Fu Jian‐Guo¹,Zhang Shu‐Sheng¹,Feng Chen‐Guo¹^ORCID

Affiliation:

1. The Research Center of Chiral Drugs Shanghai Frontiers Science Center for TCM Chemical Biology Innovation Research Institute of Traditional Chinese Medicine Shanghai University of Traditional Chinese Medicine Shanghai 201203 China

Abstract

AbstractAlkynylation of alkenyl bromoarenes via aryl to vinyl 1,4‐palladium migration/copper‐free Sonogashira coupling sequence has been developed. This approach provides a facile methodology for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes in good to excellent yields and regioselectivities.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Publisher

Wiley

Reference66 articles.

2. The Enediyne Antibiotics

3. Designed Enediyne Antitumor Agents

4. Complexity and simplicity in the biosynthesis of enediyne natural products

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stereoselective Construction of Trisubstituted 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration;Advanced Synthesis & Catalysis;2024-09-12

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