Confinement Effects in Catalysis: Steering the Product Selectivity in Cannabidiol Isomerization by the Resorcinarene Supramolecular Capsule-Reference-Cited by-同舟云学术

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Confinement Effects in Catalysis: Steering the Product Selectivity in Cannabidiol Isomerization by the Resorcinarene Supramolecular Capsule

Published:2024-04-15 Issue:16 Volume:16 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Bordignon Francesca¹²^ORCID,Calmanti Roberto¹^ORCID,Perosa Alvise¹^ORCID,Fabris Fabrizio¹^ORCID,Scarso Alessandro¹^ORCID

Affiliation:

1. Dipartimento di Scienze Molecolari e Nanosistemi Università Ca' Foscari Venezia Via Torino 155 30172 Mestre Venezia ITALY

2. Dipartimento di Scienze Chimiche Università degli studi di Padova Via Marzolo, 1 35100 Padova ITALY

Abstract

AbstractThe supramolecular hydrogen‐bonded self‐assembled resorcinarene hexameric capsule promotes the ring closing isomerization of cannabidiol through encapsulation of the intermediate carbocation species formed by protonation with HCl. The confinement effect imparted by the capsule steers product selectivity towards the uncommon products Δ8‐iso‐THC, Δ4(8)‐iso‐THC, together with the hydrated 8‐Hydroxy‐iso‐THC.

Publisher

Wiley

Reference40 articles.

1. Gas Chromatography–Mass Spectrometry Analysis of Cannabis: Undergraduate Organic Chemistry Laboratory Exercise

2. Cannabis sativa L.: Crop Management and Abiotic Factors That Affect Phytocannabinoid Production

3. A Quantitative 1H NMR Method for Screening Cannabinoids in CBD Oils

4. Concerning the Isomerization of Δ1-to Δ1(6)-Tetrahydrocannabinol1

5. Conversion of Cannabidiol (CBD) into Psychotropic Cannabinoids Including Tetrahydrocannabinol (THC): A Controversy in the Scientific Literature

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