Ultrafiltration polyanionic poly (3‐sulfopropyl methacrylate) membranes with enhanced antifouling and water flux

Author:

Khan Raja Muhammad Asif1,Nasir Habib1,Mahmood Azhar1,Iqbal Mudassir1,Janjua Hussnain A.2,Ahmad Nasir M.3ORCID

Affiliation:

1. Department of Chemistry, School of Natural Sciences National University of Sciences and Technology Islamabad Pakistan

2. Department of Industrial Biotechnology, Atta‐ur‐Rahman School of Applied Biosciences (ASAB) National University of Sciences and Technology Islamabad Pakistan

3. Polymer Research Lab, Polymer and Composite Research Group, School of Chemical and Materials Engineering (SCME) National University of Sciences and Technology Islamabad Pakistan

Abstract

AbstractPolyethersulfone (PES) membranes are prevalent in the field of water treatment owing to their exceptional separation efficiency, robust mechanical properties, and resistance to chemical degradation. Nevertheless, these membranes are prone to fouling, resulting in a decrease in both flux and ultrafiltration efficiency. In the present study, PES membranes are blended with poly (3‐Sulfopropyl Methacrylate) (PSPMA) in various weight percentages (0%–3%) to improve their antifouling and ultrafiltration properties. The physicochemical properties of the blended membranes, including surface morphology, contact angle, hydrophilicity and surface energy are evaluated. The findings indicate that incorporation PSPMA results in an enhancement of the hydrophilic properties and surface charge of the PES membranes, assessed by employing Bovine Serum Albumin (BSA) as a representative protein. Modified blended membranes display greater Flux Recovery Ratio (FRR%) and exhibit superior fouling resistance. Under the same experimental conditions (0.2 MPa applied pressure), a pure water flux of 154.18 L·m−2·h−1 for PES/PSPMA membrane found substantially greater than pure PES membrane (103.52 L·m−2·h−1) along with Total Fouling Ratio (TFR) of 36% and 64.9% respectively. Exceptional antimicrobial efficacy for modified membranes is revealed against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) using disc diffusion technique rendering them well‐suited for water treatment applications.

Publisher

Wiley

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