Affiliation:
1. Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University Guangzhou 510275 P. R. China
Abstract
AbstractWith the irradiation of visible light, α‐heteroarylation of aliphatic alcohol was selectively achieved under gentle conditions in the present of iodobenzene dichloride. The Minisci‐type cross‐dehydrogenative coupling reaction was performed in the absence of metal and acid. Readily available primary alcohols and electron‐withdrawing heteroarenes can be applied smoothly. Mechanism studies indicated that the PhICl radical and chlorine radical formed from iodobenzene dichloride were responsible for the selective hydrogen atom abstraction of alcohols.
Funder
Guangdong Science and Technology Department
Sun Yat-sen University
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Cited by
6 articles.
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