Affiliation:
1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials Science Zhejiang Normal University 688 Yingbin Road Jinhua 321004 P. R. China
Abstract
AbstractHere we report a mild protocol for benzylic C−H trifluoromethylthiolation using sodium decatungstate (NaDT) as the photocatalyst. Wherein, photoactivated DT abstracted the benzylic hydrogen atom via a radical process. This transformation works well with a slight excess of benzylic substrates or as limiting reagents for better purification. The reaction shows mild conditions and good functional group tolerance. Moreover, the protocol could be applied to gram‐scale synthesis.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Zhejiang Province
Zhejiang Normal University
Cited by
1 articles.
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