Affiliation:
1. Department of Chemistry University of Science and Technology of China 230026 Hedei P. R. China
2. State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University 730000 Lanzhou P. R. China
Abstract
AbstractPhosphine oxides and spirocyclic compounds are privileged molecules widely employed in a variety of catalytic transformations either as chiral ligands for metals or bifunctional organocatalysts. Herein, we developed a Pd‐catalysed cross‐coupling reaction to synthesize spirocyclic amino‐phosphine oxides with a P‐stereogenic centre which could serve as potential P*(O), N‐ligands or organocatalysis.
Funder
National Natural Science Foundation of China
Subject
Organic Chemistry,Physical and Theoretical Chemistry