Affiliation:
1. Max Planck Institute for Solid State Research Heisenbergstr. 1 70569 Stuttgart Germany
2. Department of Chemistry Ludwig‐Maximilians‐University (LMU) Butenandstr. 5‐13 81377 Munich Germany
3. Department of Chemistry Imperial College of London London W12 0BZ UK
4. Departamento de Física Universidad de Córdoba Campus de Rabanales Edificio Einstein (C2) Córdoba 14071 Spain
5. e‐conversion Lichtenbergstr. 4a 85748 Garching Germany
Abstract
AbstractWhile solar cell technology is booming, intermittent availability of sunlight motivates new vistas for multifunctional devices capable of energy capture and storage on the same material, i.e., direct or two‐electrode bifunctional solar batteries. Herein, simulations and experiments are utilized to take a closer look at efficiency limitations and design considerations, and guidelines are proposed to operate a solar battery comprised of the 2D carbon nitride potassium poly(heptazine imide), K‐PHI, as a bifunctional solar battery photoanode in conjunction with the separator poly(N‐vinylcarbazole) and cathode poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate. An optical design of this device is developed by proposing light absorption in a charge collection layer within the photoanode and calculating photocharging current and charging time as figures of merit. The much larger efficiency of operation via rear illumination for K‐PHI layer thicknesses >200 nm is highlighted and enhancement strategies without modifying the photoactive layer are proposed. Finally, adapted Ragone plots are introduced and it is shown how the solar batteries are capable of improving energy and charge output solely via illumination (for the design under 1 sun, the energy and charge output increase by 60% and 63%, respectively) without modifying the device.
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献