Pressure and solvent effects on the kinetics of a Menshutkin reaction in aliphatic alcohols
Author:
Publisher
Wiley
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Reference27 articles.
1. Activation and reaction volumes in solution
2. Study of initial state and transition state solvation in the Menschutkin reaction of triethylamine with ethyl iodide in alcohols from infinite dilution activity coefficients
3. Interpretation of Hydroxylic Solvent Effects Based on Correlations with Solvent Parameters. Reaction of Et3N with EtI
4. Solvent Effect under High Pressure. A Novel Procedure for the Estimation of the Activation Volume and an Abnormal Acceleration of Reaction under High Pressure
Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Theoretical analysis of high-pressure effects on conformational equilibria;Canadian Journal of Chemistry;2018-02
2. A comparative analysis of empirical equations describing pressure dependence of equilibrium and reaction rate constants;Canadian Journal of Chemistry;2017-02
3. On the Effect of Enhanced Mass Transfer on Side Reactions in Capillary Microreactors during High-Temperature Synthesis of an Ionic Liquid;Chemical Engineering & Technology;2009-11
4. Unusual Solvent Effect on a SN2 Reaction. A Quantum-Mechanical and Kinetic Study of the Menshutkin Reaction between 2-Amino-1-methylbenzimidazole and Iodomethane in the Gas Phase and in Acetonitrile;The Journal of Physical Chemistry B;2006-01-07
5. The quaternisation reaction of phosphines and amines in aliphatic alcohols. A similarity analysis using the isokinetic, isosolvent and isoselective relationshipsElectronic supplementary information (ESI) available: Table S1 containing literature values of solvent parameters for alkan-1-ols in five different scales and Table S2 with rate constants for the quaternisation of triethylamine by iodoethane at different temperatures in methanol, ethanol, propan-1-ol and butan-1-ol. See http://www.rsc.org/suppdata/ob/b3/b316556f;Organic & Biomolecular Chemistry;2004
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