Facile Hydrothermal Synthesis of Visible‐Light‐Driven MnS/rGO Nanocomposite for Photocatalytic Degradation of Methylene Blue Dye

Author:

Saleem Ammar1,Alharbi Fatemah Farraj2,Ashiq Muhammad Naeem1,Manzoor Sumaira1,Abbas Shah Syed Imran1,Khan Komal Zaman1,Aman Salma3ORCID,Ahmad Naseeb3,Alzahrani Huda A.4,Messali Mouslim5

Affiliation:

1. Institute of Chemical Sciences Bahauddin Zakariya University Multan 60800 Pakistan

2. Department of physics College of Science Princess Nourah bint Abdulrahman University P.O. Box 84428 Riyadh 11671 Saudi Arabia

3. Institute of Physics Khwaja Fareed University of Engineering and Information Technology Abu Dhabi Road Rahim Yar Khan 64200 Pakistan

4. Department of Physics College of Science Taif University P.O. Box 11099 Taif 21944 Saudi Arabia

5. Department of Chemistry College of Science Imam Mohammad Ibn Saud Islamic University P.O. Box, 90950 Riyadh 11623 Saudi Arabia

Abstract

Currently, the global problem of poisonous and nondegradable organic water pollutants cannot be ignored. Heterogeneous photocatalysis is an advanced oxidation process (AOP) that uses semiconducting materials as a catalyst to clean water. Nanosize semiconductor photocatalysts are well recognized for their practical and cost‐effective way of cleaning up environmental pollution when exposed to visible light. Herein, a simple hydrothermal approach is used to create an MnS/rGO nanocomposite for the degradation of aromatic dyes under visible light. Powder X‐ray diffraction, scanning electron microscopy, and UV–visible spectroscopy are utilized to analyze the synthesized photocatalyst. Methylene blue is investigated for photocatalytic degradation using the MnS/rGO heterostructure nanocomposite. Under visible light, the composite shows photocatalytic degradation efficiency of 91.8% owing to the addition of rGO, its synergistic effects, high specific surface area, and a decrease in photoinduced electron–hole pair recombination. The fabricated nanocomposite MnS/rGO with significantly better photoresponse activity is successfully protected from charge recombination by reduced graphene oxide, which functions as a superb electron‐carrying material.

Publisher

Wiley

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics,Electronic, Optical and Magnetic Materials

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